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Rh(I)-Catalyzed Decarbonylative Spirocyclization via C–C Cleavage of Benzocyclobutenones: An Efficient Approach to Access Functionalized Spirocycles
We describe a rhodium-catalyzed all-carbon spirocenter formation through a decarbonylative coupling of trisubstituted cyclic olefins and benzocyclobutenones via C–C activation. A [Rh(CO)(2)Cl](2)/P(C(6)F(5))(3) metal-ligand combination was found to catalyze this transformation most efficiently. A ra...
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| Hauptverfasser: | , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2014
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3970409/ https://ncbi.nlm.nih.gov/pubmed/24446067 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201310149 |
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