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Rh-Catalyzed Decarbonylative Coupling with Alkynes via C–C Activation of Isatins

Herein we report a [5+2-1] transformation though catalytic decarbonylative coupling between isatins and alkynes, which provides a unique way to synthesize 2-quinolinone derivatives. A broad range of alkynes can be coupled efficiently with high regioselectivity. This reaction is proposed to go throug...

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Bibliografske podrobnosti
izdano v:J Am Chem Soc
Main Authors: Zeng, Rong, Dong, Guangbin
Format: Artigo
Jezik:Inglês
Izdano: 2015
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC4452207/
https://ncbi.nlm.nih.gov/pubmed/25569352
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja512306a
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