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Nature-Inspired Stereospecific Total Synthesis of P-(+)-Dispegatrine as well as the Total Synthesis of Four Other Monomeric Sarpagine Indole Alkaloids
Non-phenolic oxidative coupling: The first total synthesis of the C-2 symmetric indole alkaloid P-(+)-dispegatrine (1) is reported. A late-stage thallium(III)acetate mediated intermolecular oxidative coupling was employed to construct the C(9)-C(9′) bond with complete regio- and stereocontrol. The e...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3970238/ https://ncbi.nlm.nih.gov/pubmed/23073985 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201206015 |
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