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Highly enantioselective epoxidation of styrenes: Implication of an electronic effect on the competition between spiro and planar transition states
Asymmetric epoxidation of various styrenes using carbocyclic oxazolidinone-containing ketone 3 has been investigated. High enantioselectivity (89–93% enantiomeric excess) has been attained for this challenging class of alkenes. Mechanistic studies show that substituents on the ketone catalyst can ha...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
National Academy of Sciences
2004
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC395987/ https://ncbi.nlm.nih.gov/pubmed/15069190 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0307548101 |
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