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Enantioselective direct aldol reactions catalyzed by l-prolinamide derivatives

l-Prolinamides 2, prepared from l-proline and simple aliphatic and aromatic amines, have been found to be active catalysts for the direct aldol reaction of 4-nitrobenzaldehyde with neat acetone at room temperature. They give moderate enantioselectivities of up to 46% enantiomeric excess (ee). The en...

Disgrifiad llawn

Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Cyhoeddwyd yn:Proc Natl Acad Sci U S A
Prif Awduron: Tang, Zhuo, Jiang, Fan, Cui, Xin, Gong, Liu-Zhu, Mi, Ai-Qiao, Jiang, Yao-Zhong, Wu, Yun-Dong
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: National Academy of Sciences 2004
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC395980/
https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/15079057/
https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.0307176101
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