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A Synthesis of the Tetracyclic Core of Exiguaquinol
[Image: see text] A Diels–Alder reaction, a desymmetrizing aldol reaction, and a reductive Heck cyclization are employed in a short synthesis of a tetracycle relevant to exiguaquinol, a potential antibiotic. Ground-state energies of this advanced model system and the natural product rationalize the...
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| Главные авторы: | , , , , |
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| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
2013
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3946388/ https://ncbi.nlm.nih.gov/pubmed/24219829 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol402905n |
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