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Aminofluorination of 2-alkynylanilines: a Au-catalyzed entry to fluorinated indoles

The scope and limitations of gold-catalyzed tandem cycloisomerization/fluorination reactions of unprotected 2-alkynylanilines to have access to 3,3-difluoro-2-aryl-3H-indoles and 3-fluoro-2-arylindoles are described. An unprecedented aminoauration/oxidation/fluorination cascade reaction of 2-alkynyl...

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Détails bibliographiques
Auteurs principaux: Arcadi, Antonio, Pietropaolo, Emanuela, Alvino, Antonello, Michelet, Véronique
Format: Artigo
Langue:Inglês
Publié: Beilstein-Institut 2014
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC3943415/
https://ncbi.nlm.nih.gov/pubmed/24605165
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.10.42
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