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One-pot gold-catalyzed synthesis of 3-silylethynyl indoles from unprotected o-alkynylanilines
The Au(III)-catalyzed cyclization of 2-alkynylanilines was combined in a one-pot procedure with the Au(I)-catalyzed C3-selective direct alkynylation of indoles using the benziodoxolone reagent TIPS-EBX to give a mild, easy and straightforward entry to 2-substituted-3-alkynylindoles. The reaction can...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Beilstein-Institut
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3107533/ https://ncbi.nlm.nih.gov/pubmed/21647264 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.7.65 |
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