Structure of the oxygen adduct intermediate in the bacterial luciferase reaction: (13)C nuclear magnetic resonance determination

By using FMN enriched in (13)C (90%) at position C-4a, we have conclusively shown that the reaction of molecular oxygen with bacterial luciferase-bound FMNH(2) forms an adduct at the 4a position. Consistent with this are (13)C NMR studies of FMN and other flavin compounds which show that this carbon...

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Pubblicato in:	Proc Natl Acad Sci U S A
Autori principali:	Ghisla, Sandro, Hastings, J. Woodland, Favaudon, Vincent, Lhoste, Jean-Marc
Natura:	Artigo
Lingua:	Inglês
Pubblicazione:	National Academy of Sciences 1978
Soggetti:	Biological Sciences: Biochemistry
Accesso online:	https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC393075/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/16592595/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.75.12.5860
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