Structure of the oxygen adduct intermediate in the bacterial luciferase reaction: (13)C nuclear magnetic resonance determination

By using FMN enriched in (13)C (90%) at position C-4a, we have conclusively shown that the reaction of molecular oxygen with bacterial luciferase-bound FMNH(2) forms an adduct at the 4a position. Consistent with this are (13)C NMR studies of FMN and other flavin compounds which show that this carbon...

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Hlavní autoři: Ghisla, Sandro, Hastings, J. Woodland, Favaudon, Vincent, Lhoste, Jean-Marc
Médium: Artigo
Jazyk:Inglês
Vydáno: 1978
Témata:
Biological Sciences: Biochemistry
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC393075/
https://ncbi.nlm.nih.gov/pubmed/16592595
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