Development of Stereocontrolled Palladium(II)-Catalyzed Domino Heck/Suzuki β,α-Diarylation Reactions with Chelating Vinyl Ethers and Arylboronic Acids

A stereoselective and 1,4-benzoquinone-mediated palladium(II)-catalyzed Heck/Suzuki domino reaction involving metal coordinating cyclic methylamino vinyl ethers and a number of electronically diverse arylboronic acids has been developed and studied. Diastereomeric ratios up to 39:1 and 78 % isolated...

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Bibliographic Details
Main Authors: Trejos, Alejandro, Odell, Luke R, Larhed, Mats
Format: Artigo
Language:Inglês
Published: WILEY-VCH Verlag 2012
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Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3922440/
https://ncbi.nlm.nih.gov/pubmed/24551492
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/open.201100010
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