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Mechanistic Studies for Palladium Catalyzed Copolymerization of Ethylene with Vinyl Ethers

The mechanism of ethylene with vinyl ether (VE, CH(2)=CHOEt) copolymerization catalyzed by phosphine-sulfonate palladium complex (A) was investigated by density functional theory (DFT) calculation. On achieving an agreement between theory and experiment, it is found that the favorable 1,2-selective...

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Publicado en:Polymers (Basel)
Main Authors: Mehmood, Andleeb, Xu, Xiaowei, Raza, Waseem, Kim, Ki-Hyun, Luo, Yi
Formato: Artigo
Idioma:Inglês
Publicado: MDPI 2020
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC7603233/
https://ncbi.nlm.nih.gov/pubmed/33086515
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/polym12102401
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