Transmetallation Versus β-Hydride Elimination: The Role of 1,4-Benzoquinone in Chelation-Controlled Arylation Reactions with Arylboronic Acids

AbstractThe formation of an atypical, saturated, diarylated, Heck/Suzuki, domino product produced under oxidative Heck reaction conditions, employing arylboronic acids and a chelating vinyl ether, has been investigated by DFT calculations. The calculations highlight the crucial role of 1,4-benzoquin...

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Detalhes bibliográficos
Main Authors: Sköld, Christian, Kleimark, Jonatan, Trejos, Alejandro, Odell, Luke R, Nilsson Lill, Sten O, Norrby, Per-Ola, Larhed, Mats
Formato: Artigo
Idioma:Inglês
Publicado em: WILEY-VCH Verlag 2012
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3531627/
https://ncbi.nlm.nih.gov/pubmed/22374849
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201102678
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