Decarboxylative Palladium(II)-Catalyzed Synthesis of Aryl Amidines from Aryl Carboxylic Acids: Development and Mechanistic Investigation

A fast and convenient synthesis of aryl amidines starting from carboxylic acids and cyanamides is reported. The reaction was achieved by palladium(II)-catalysis in a one-step microwave protocol using [Pd(O(2)CCF(3))(2)], 6-methyl-2,2′-bipyridyl and trifluoroacetic acid (TFA) in N-methylpyrrolidinone...

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Main Authors: Rydfjord, Jonas, Svensson, Fredrik, Trejos, Alejandro, Sjöberg, Per J R, Sköld, Christian, Sävmarker, Jonas, Odell, Luke R, Larhed, Mats
Formato: Artigo
Idioma:Inglês
Publicado em: WILEY-VCH Verlag 2013
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3935511/
https://ncbi.nlm.nih.gov/pubmed/23983102
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201301809
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