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Substituent Effects on the Formation and Nucleophile Selectivity of Ring-Substituted Phenonium Ions in Aqueous Solution
The reaction of 2-(4-methyphenyl)ethyl tosylate (Me-1-OTs) in 50/50 (v/v) trifluoroethanol/water at 25 °C is first-order in the concentration of azide anion nucleophile. A carbon-13 NMR analysis of the products of the reactions of Me-1-[α–(13)C]OTs in 50/50 (v/v) trifluoroethanol/water at 25 °C show...
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| Main Authors: | , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2013
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3913281/ https://ncbi.nlm.nih.gov/pubmed/24511183 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/poc.3145 |
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