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Formation and Stability of the 4-Methoxyphenonium Ion in Aqueous Solution

The reaction of 2-methoxyphenylethyl tosylate (MeO-1-Ts) is first-order in [N(3)(−)]. A carbon-13 NMR analysis of the products of the reactions of MeO-1-[α–(13)C]Ts shows the formation of MeO-1-[β–(13)C]OH and MeO-1-[β–(13)C]N(3) from the trapping of a symmetrical 4-methoxyphenonium ion reaction int...

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Detalhes bibliográficos
Main Authors: Tsuji, Yutaka, Hara, Daisuke, Hagimoto, Rui, Richard, John P.
Formato: Artigo
Idioma:Inglês
Publicado em: 2011
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3225690/
https://ncbi.nlm.nih.gov/pubmed/22029847
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo202118s
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