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Selective Syntheses of Δ(α,β) and Δ(β,γ) Butenolides from Allylic Cyclopropenecarboxylates via Tandem Ring Expansion/[3,3]-Sigmatropic Rearrangements

[Image: see text] Allylic cyclopropenecarboxylates undergo ring expansion reactions to give 2-allyloxyfuran intermediates, which subsequently rearrange to Δ(β,γ) butenolides via Claisen rearrangement or to the corresponding Δ(α,β) butenolides via further Cope rearrangement. Also described are method...

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Detaylı Bibliyografya
Asıl Yazarlar: Xie, Xiaocong, Li, Yi, Fox, Joseph M.
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: 2013
Konular:
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC3908874/
https://ncbi.nlm.nih.gov/pubmed/23514430
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol400264a
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