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A thermally-induced, tandem [3,3]-sigmatropic rearrangement/[2 + 2] cycloaddition approach to carbocyclic spirooxindoles

The synthesis of C3-carbocyclic spirooxindoles was realized by way of an intramolecular [2 + 2] cycloaddition reaction between a vinylidene indolin-2-one and an alkyne. The cycloaddition reaction occurs selectively with the distal double bond of the allene, is tolerant of a phenyl and trimethylsilyl...

詳細記述

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書誌詳細
主要な著者: Brummond, Kay M, Osbourn, Joshua M
フォーマット: Artigo
言語:Inglês
出版事項: Beilstein-Institut 2010
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC2874392/
https://ncbi.nlm.nih.gov/pubmed/20502602
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.6.33
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