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Entropic Contributions to Rate Accelerations in Enzymic and Intramolecular Reactions and the Chelate Effect

It is pointed out that translational and (overall) rotational motions provide the important entropic driving force for enzymic and intramolecular rate accelerations and the chelate effect; internal rotations and unusually severe orientational requirements are generally of secondary importance. The l...

Deskribapen osoa

Gorde:
Xehetasun bibliografikoak
Egile Nagusiak: Page, Michael I., Jencks, William P.
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: 1971
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC389269/
https://ncbi.nlm.nih.gov/pubmed/5288752
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