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Synthesis of the Spiroiminal Moiety and Approaches to the Synthesis of Marineosins A and B
A short and efficient synthesis of model spiroiminals that have the same stereochemistry but different conformations than marineosins A and B was carried out in 6-7 steps from 6-methyltetrahydropyran-2-one. These spiroiminals were also prepared biomimetically by reduction of an enol ether. A more hi...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3885995/ https://ncbi.nlm.nih.gov/pubmed/24199754 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo402178r |
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