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A gold-catalysed enantioselective Cope rearrangement of achiral 1,5-dienes
Since the discovery of the Cope rearrangement in the 1940s, no asymmetric variant of the rearrangement of achiral 1,5-dienes has emerged, despite the successes that have been achieved with its heteroatom variants (Claisen, aza-Cope, etc.). This article reports the first example of an enantioselectiv...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3882197/ https://ncbi.nlm.nih.gov/pubmed/22522261 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/nchem.1327 |
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