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Gold(I)-Catalyzed Formation of Bicyclo[4.2.0]oct-1-enes

[Image: see text] Gold(I) catalysts effectively promote the Cope rearrangement of acyclic 1,5-dienes bearing a terminal cyclopropylidene. When this methodology is applied to cyclic substrates an unexpected transformation occurs, resulting in the formation of a tricyclic compound incorporating a bicy...

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Autors principals: Felix, Ryan J., Gutierrez, Osvaldo, Tantillo, Dean J., Gagné, Michel R.
Format: Artigo
Idioma:Inglês
Publicat: 2013
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3788353/
https://ncbi.nlm.nih.gov/pubmed/23663099
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo400139g
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