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Multimetallic Cooperativity in Activation of Dinitrogen at Iron-Potassium Sites

The reaction of soluble iron-oxygen-potassium assemblies with N(2) gives insight into the mechanisms of multimetallic N(2) coordination. We report a series of very electron-rich three-coordinate, β-diketiminate-supported iron(I) phenoxide complexes, which are metastable but have been characterized u...

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Hlavní autoři: Chiang, Karen P., Bellows, Sarina M., Brennessel, William W., Holland, Patrick L.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2013
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3873751/
https://ncbi.nlm.nih.gov/pubmed/24379972
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C3SC52487F
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