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Effects of Ligand Halogenation on the Electron Localization, Geometry and Spin State of Low-Coordinate (β-Diketiminato)iron Complexes
This contribution explores the influences of incorporating electron-withdrawing CF(3) and halide groups into β-diketiminate iron complexes of tetrazene and isocyanide. The synthesis of a new halogenated β-diketimine (L(CF3,Cl)H) was accomplished via two different methods, including a novel microwave...
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| Publicado no: | Eur J Inorg Chem |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5563838/ https://ncbi.nlm.nih.gov/pubmed/28835739 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejic.201600112 |
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