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Ligand Orientation Control in Low-Spin Six-Coordinate (Porphinato)iron(II) Species
The synthesis of a low-spin six-coordinate iron(II) porphyrinate in which the two axial ligands are forced to have a relative perpendicular orientation has been successfully accomplished for the first time. The reaction of four-coordinate (tetramesitylporphinato)iron(II) with 2-methylimidazole leads...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2005
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1502394/ https://ncbi.nlm.nih.gov/pubmed/15934765 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic050320p |
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