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Electronic Configuration of High-Spin Imidazole-Ligated Iron(II) Octaethyl-porphyrinates
The preparation and characterization of two new five-coordinate, imidazole- ligated, high-spin iron(II) octaethylporphyrinates is described. [Fe(OEP)(1,2-Me(2)Im)] and [Fe-(OEP)(2-MeHIm)] have been characterized by X-ray structure determinations and temperaturedependent Mössbauer spectroscopy in zer...
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| Главные авторы: | , , , , |
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| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
2006
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1525298/ https://ncbi.nlm.nih.gov/pubmed/16676979 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic052194v |
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