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EPR and Mössbauer Spectroscopy, and DFT Analysis of a High-Spin Fe(IV)-oxo Complex
The kinetically competent oxidant in non-heme iron enzymes is a high-spin Fe(IV)-oxo species, which are not as well characterized as the intermediate-spin species of heme systems. The present work gives a detailed characterization of the structurally similar [Fe(IV)H(3)buea(O)](-), [Fe(III)H(3)buea(...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3869391/ https://ncbi.nlm.nih.gov/pubmed/22574962 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja303224p |
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