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Synthesis of the spiroketal core of integramycin

A concise synthetic strategy towards the spiroketal core of the HIV-integrase inhibitor integramycin (1) was developed. The required ketone precursor was efficiently constructed from two simple and easily accessible subunits by means of a hydrozirconation/copper catalyzed acylation reaction. The eff...

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Detalhes bibliográficos
Autor principal: Prusov, Evgeny V
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3869345/
https://ncbi.nlm.nih.gov/pubmed/24367411
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.9.282
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