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The total synthesis of D-chalcose and its C-3 epimer
We completed a new and efficient synthesis of D-chalcose (I) and the first synthesis of its C-3 epimer (I′) in nine steps with overall yields of 23% and 24%, respectively. The key steps in the sequence were the formation of the stereocenter on C3 via Grignard reaction, the introduction of the stereo...
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| Autors principals: | , , , , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
Beilstein-Institut
2013
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3869251/ https://ncbi.nlm.nih.gov/pubmed/24367425 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.9.296 |
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