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Reactions of a Chromium(III)-Superoxo Complex and Nitric Oxide That Lead to the Formation of Chromium(IV)-Oxo and Chromium(III)-Nitrito Complexes

The reaction of an end-on Cr(III)-superoxo complex bearing a 14-membered tetraazamacrocyclic TMC ligand, [Cr(III)(14-TMC)(O(2))(Cl)](+), with nitric oxide (NO) resulted in the generation of a stable Cr(IV)-oxo species, [Cr(IV)(14-TMC)(O)(Cl)](+), via the formation of a Cr(III)-peroxynitrite intermed...

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Hlavní autoři: Yokoyama, Atsutoshi, Cho, Kyung-Bin, Karlin, Kenneth D., Nam, Wonwoo
Médium: Artigo
Jazyk:Inglês
Vydáno: 2013
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3864658/
https://ncbi.nlm.nih.gov/pubmed/24066924
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja405891n
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