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Unexpected reactivity of 2-fluorolinalyl diphosphate in the active site of crystalline 2-methylisoborneol synthase

The crystal structure of 2-methylisoborneol synthase (MIBS) from Streptomyces coelicolor A3(2) has been determined in its unliganded state and in complex with 2 Mg(2+) ions and cis-2-fluorogeranyl diphosphate at 1.85 Å and 2.00 Å resolution, respectively. Under normal circumstances, MIBS catalyzes t...

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Autors principals: Köksal, Mustafa, Chou, Wayne K. W., Cane, David E., Christianson, David W.
Format: Artigo
Idioma:Inglês
Publicat: 2013
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3859731/
https://ncbi.nlm.nih.gov/pubmed/23844678
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi400797c
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