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Changing hydration level in an internal cavity modulates the proton affinity of a key glutamate in cytochrome c oxidase

Cytochrome c oxidase contributes to the transmembrane proton gradient by removing two protons from the high-pH side of the membrane each time the binuclear center active site is reduced. One proton goes to the binuclear center, whereas the other is pumped to the low-pH periplasmic space. Glutamate 2...

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Autori principali: Goyal, Puja, Lu, Jianxun, Yang, Shuo, Gunner, M. R., Cui, Qiang
Natura: Artigo
Lingua:Inglês
Pubblicazione: National Academy of Sciences 2013
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC3839721/
https://ncbi.nlm.nih.gov/pubmed/24198332
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1313908110
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