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Stereoselective Nucleoside Deuteration for NMR Studies of DNA
A procedure has been elaborated for stereoselective deuterium substitution of one of the diastereotopic 5′-protons in 2′-deoxynucleotides. The synthetic scheme uses the reduction of the 5-oxosugar derivative with deuterated Alpine-Borane. The resulting deuterosugar is converted into pyrimidine nucle...
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| Main Authors: | , |
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| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
2010
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3836267/ https://ncbi.nlm.nih.gov/pubmed/20589575 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1080/15257770.2010.494650 |
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