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Highly Z-Selective and Enantioselective Ring Opening/Cross Metathesis Catalyzed by Resolved Stereogenic-At-Ru Complex
The synthesis of a ruthenium complex that catalyzes Z-selective (up to 98% Z) asymmetric ring opening/cross metathesis with high enantioselectivity (up to 95% ee) is reported. Synthesis of the catalyst features the resolution of a chelating NHC alkylidene complex by ligand substitution with a chiral...
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| Hlavní autoři: | , |
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| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
2013
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3826570/ https://ncbi.nlm.nih.gov/pubmed/23822901 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja4046422 |
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