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Enol Ethers as Substrates for Efficient Z- and Enantioselective Ring-Opening/Cross-Metathesis Reactions Promoted by Stereogenic-at-Mo Complexes. Utility in Chemical Synthesis and Mechanistic Attributes

[Image: see text] The first examples of catalytic enantioselective ring-opening/cross-metathesis (EROCM) reactions that involve enol ethers are reported. Specifically, we demonstrate that catalytic EROCM of several oxa- and azabicycles, cyclobutenes and a cyclopropene with an alkyl- or aryl-substitu...

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Detalhes bibliográficos
Main Authors: Yu, Miao, Ibrahem, Ismail, Hasegawa, Masayuki, Schrock, Richard R., Hoveyda, Amir H.
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3298191/
https://ncbi.nlm.nih.gov/pubmed/22272931
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja210946z
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