The Significance of Degenerate Processes to Enantioselective Olefin Metathesis Reactions Promoted by Stereogenic-at-Mo Complexes

The present study provides spectroscopic and experimental evidence demonstrating that degenerate metathesis is critical to the effectiveness of this emerging class of chiral catalysts. Isolation and characterization (X-ray) of both diastereomeric complexes, as well as examination of the reactivity a...

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Hauptverfasser: Meek, Simon J., Malcolmson, Steven J., Li, Bo, Schrock, Richard R., Hoveyda, Amir H.
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2009
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Article
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2783322/
https://ncbi.nlm.nih.gov/pubmed/19842640
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja907805f
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