The synthesis of open-shell, bimetallic Mn/Fe trinuclear clusters

Concomitant deprotonation and metallation of hexadentate ligand platform (tbs)LH(6) ((tbs)LH(6) = 1,3,5-C(6)H(9)(NHC(6)H(4)-o-NHSiMe(2) (t)Bu)(3)) with divalent transition metal starting materials Fe(2)(Mes)(4) (Mes = mesityl) or Mn(3)(Mes)(6) in the presence of tetrahydrofuran (THF) resulted in iso...

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Main Authors: Powers, Tamara M., Gu, Nina, Fout, Alison R., Baldwin, Anne M., Sánchez, Raúl Hernández, Alfonso, Denise M., Chen, Yu-Sheng, Zheng, Shao-Liang, Betley, Theodore A.
Format: Artigo
Sprog:Inglês
Udgivet: 2013
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Article
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3822335/
https://ncbi.nlm.nih.gov/pubmed/23984911
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja408003d
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