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Maximizing Electron Exchange in a [Fe(3)] Cluster
The one-electron reduction of ((tbs)L)Fe(3)(thf)(1) furnishes [M][((tbs)L)Fe(3)] ([M](+) = [(18-C-6)K(thf)(2)](+) (1, 76%) or [(crypt-222)K](+) (2, 54%)). Upon reduction, the ligand (tbs)L(6−) rearranges around the triiron core to adopt an almost ideal C(3)-symmetry. Accompanying the ((tbs)L) ligand...
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| Pubblicato in: | J Am Chem Soc |
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| Autori principali: | , , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2016
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5567842/ https://ncbi.nlm.nih.gov/pubmed/26799500 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b12181 |
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