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Oxidative group transfer to a trimanganese complex to form Mn(6)(μ(6)-E) (E = O, N) clusters featuring interstitial oxide and nitride functionalities
Utilizing a hexadentate ligand platform, a trinuclear manganese complex of the type ((H)L)Mn(3)(thf)3 was synthesized and characterized ([(H)L](6−) = [MeC(CH(2)N(C(6)H(4)-o-NH))(3)](6−)). The pale orange, formally divalent trimanganese complex rapidly reacts with O-atom transfer reagents to afford t...
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| Hoofdauteurs: | , , , |
|---|---|
| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
2011
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| Onderwerpen: | |
| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3201831/ https://ncbi.nlm.nih.gov/pubmed/21942370 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja2066384 |
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