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Oxidative group transfer to a trimanganese complex to form Mn(6)(μ(6)-E) (E = O, N) clusters featuring interstitial oxide and nitride functionalities

Utilizing a hexadentate ligand platform, a trinuclear manganese complex of the type ((H)L)Mn(3)(thf)3 was synthesized and characterized ([(H)L](6−) = [MeC(CH(2)N(C(6)H(4)-o-NH))(3)](6−)). The pale orange, formally divalent trimanganese complex rapidly reacts with O-atom transfer reagents to afford t...

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Detalhes bibliográficos
Main Authors: Fout, Alison R., Zhao, Qinliang, Xiao, Dianne J., Betley, Theodore A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2011
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3201831/
https://ncbi.nlm.nih.gov/pubmed/21942370
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja2066384
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