Trigonal Mn(3) and Co(3) Clusters Supported by Weak-Field Ligands: A Structural, Spectroscopic, Magnetic, and Computational Investigation into the Correlation of Molecular and Electronic Structure

Transamination of divalent transition metal starting materials (M(2)(N(SiMe(3))(2))(4), M = Mn, Co) with hexadentate ligand platforms (R)LH(6) ((R)LH(6) = MeC(CH(2)NPh-o-NR)(3) where R = H, Ph, Mes (Mes = Mesityl)) or (H,Cy)LH(6) = 1,3,5-C(6)H(9)(NHPh-o-NH(2))(3) with added pyridine or tertiary phos...

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Detalhes bibliográficos
Main Authors: Fout, Alison R., Xiao, Dianne J., Zhao, Qinliang, Harris, T. David, King, Evan R., Eames, Emily V., Zheng, Shao-Liang, Betley, Theodore A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3479444/
https://ncbi.nlm.nih.gov/pubmed/22991939
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic301278m
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