Enediolate-Dilithium Amide Mixed Aggregates in the Enantioselective Alkylation of Arylacetic Acids: Structural Studies and a Stereochemical Model

A combination of X-ray crystallography, (6)Li, (15)N, and (13)C NMR spectroscopies, and density functional theory computations afford insight into the structures and reactivities of intervening aggregates underlying highly selective asymmetric alkylations of carboxylic acid dianions (enediolates) me...

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Hlavní autoři: Ma, Yun, Stivala, Craig E., Wright, Ashley M., Hayton, Trevor, Liang, Jun, Keresztes, Ivan, Lobkovsky, Emil, Collum, David B., Zakarian, Armen
Médium: Artigo
Jazyk:Inglês
Vydáno: 2013
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3818356/
https://ncbi.nlm.nih.gov/pubmed/23654300
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja403076u
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