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A concise enantioselective synthesis of the guaiane sesquiterpene (−)-oxyphyllol
(−)-Oxyphyllol was prepared in only 4 steps from an epoxy enone that already served as an intermediate for the total synthesis of the anticancer guaiane (−)-englerin A. A regio- and diastereoselective Co(II)-catalyzed hydration of the olefin and a transannular epoxide opening were used as the key re...
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| Główni autorzy: | , |
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| Format: | Artigo |
| Język: | Inglês |
| Wydane: |
Beilstein-Institut
2013
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| Hasła przedmiotowe: | |
| Dostęp online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3817518/ https://ncbi.nlm.nih.gov/pubmed/24204414 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.9.239 |
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