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A concise enantioselective synthesis of the guaiane sesquiterpene (−)-oxyphyllol

(−)-Oxyphyllol was prepared in only 4 steps from an epoxy enone that already served as an intermediate for the total synthesis of the anticancer guaiane (−)-englerin A. A regio- and diastereoselective Co(II)-catalyzed hydration of the olefin and a transannular epoxide opening were used as the key re...

Deskribapen osoa

Gorde:
Xehetasun bibliografikoak
Egile Nagusiak: Zahel, Martin, Metz, Peter
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: Beilstein-Institut 2013
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC3817518/
https://ncbi.nlm.nih.gov/pubmed/24204414
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.9.239
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