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Role of Oxido Incorporation and Ligand Lability in Expanding Redox Accessibility of Structurally Related Mn(4) Clusters

Photosystem II supports four manganese centers through nine oxidation states from manganese(II) during assembly through to the most oxidized state before O(2) formation and release. The protein-based carboxylate and imidazole ligands allow for significant changes of the coordination environment duri...

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Autors principals: Kanady, Jacob S., Tran, Rosalie, Stull, Jamie A., Lu, Luo, Stich, Troy A., Day, Michael W., Yano, Junko, Britt, R. David, Agapie, Theodor
Format: Artigo
Idioma:Inglês
Publicat: 2013
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3806640/
https://ncbi.nlm.nih.gov/pubmed/24163730
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C3SC51406D
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