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Role of Oxido Incorporation and Ligand Lability in Expanding Redox Accessibility of Structurally Related Mn(4) Clusters
Photosystem II supports four manganese centers through nine oxidation states from manganese(II) during assembly through to the most oxidized state before O(2) formation and release. The protein-based carboxylate and imidazole ligands allow for significant changes of the coordination environment duri...
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Main Authors: | , , , , , , , , |
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Formato: | Artigo |
Idioma: | Inglês |
Publicado em: |
2013
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Assuntos: | |
Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3806640/ https://ncbi.nlm.nih.gov/pubmed/24163730 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C3SC51406D |
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