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Aerobic Dehydrogenation of Cyclohexanone to Phenol Catalyzed by Pd(TFA)(2)/2-Dimethylaminopyridine: Evidence for the Role of Pd-Nanoparticles
We have carried out a mechanistic investigation of aerobic dehydrogenation of cyclohexanones and cyclohexenones to phenols with a Pd(TFA)(2)/2-dimethylaminopyridine (2-Me(2)Npy) catalyst system. Numerous experimental methods, including kinetic studies, filtration tests, Hg poisoning experiments, tra...
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| Main Authors: | , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2013
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3796041/ https://ncbi.nlm.nih.gov/pubmed/23662607 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja403165u |
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