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Aerobic Dehydrogenation of Cyclohexanone to Phenol Catalyzed by Pd(TFA)(2)/2-Dimethylaminopyridine: Evidence for the Role of Pd-Nanoparticles

We have carried out a mechanistic investigation of aerobic dehydrogenation of cyclohexanones and cyclohexenones to phenols with a Pd(TFA)(2)/2-dimethylaminopyridine (2-Me(2)Npy) catalyst system. Numerous experimental methods, including kinetic studies, filtration tests, Hg poisoning experiments, tra...

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Bibliografiske detaljer
Main Authors: Pun, Doris, Diao, Tianning, Stahl, Shannon S.
Format: Artigo
Sprog:Inglês
Udgivet: 2013
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3796041/
https://ncbi.nlm.nih.gov/pubmed/23662607
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja403165u
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