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Direct Aerobic α, β-Dehydrogenation of Aldehydes and Ketones with a Pd(TFA)(2)/4,5-Diazafluorenone Catalyst()

The direct α, β-dehydrogenation of aldehydes and ketones represents an efficient alternative to stepwise methods to prepare enal and enone products. Here, we describe a new Pd(TFA)(2)/4,5-diazafluorenone dehydrogenation catalyst that overcomes key limitations of previous catalyst systems. The scope...

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Detalhes bibliográficos
Main Authors: Diao, Tianning, Wadzinski, Tyler J., Stahl, Shannon S.
Formato: Artigo
Idioma:Inglês
Publicado em: 2011
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3370690/
https://ncbi.nlm.nih.gov/pubmed/22690316
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C1SC00724F
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