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Characterization of DMSO Coordination to Palladium(II) in Solution and Insights into the Aerobic Oxidation Catalyst, Pd(DMSO)(2)(TFA)(2)

Recent studies have shown that Pd(DMSO)(2)(TFA)(2) (TFA = trifluoroacetate) is an effective catalyst for a number of different aerobic oxidation reactions. Here, we provide insights into the coordination properties of DMSO to palladium(II) in both the solid state and in solution. A crystal structure...

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Detalhes bibliográficos
Main Authors: Diao, Tianning, White, Paul, Guzei, Ilia, Stahl, Shannon S.
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3494491/
https://ncbi.nlm.nih.gov/pubmed/23092381
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic301799p
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