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Aerobic Dehydrogenation of Cyclohexanone to Cyclohexenone Catalyzed by Pd(DMSO)(2)(TFA)(2): Evidence for Ligand-Controlled Chemoselectivity
The dehydrogenation of cyclohexanones affords cyclohexenones or phenols via removal of one or two equivalents of H(2), respectively. We recently reported several Pd(II) catalyst systems that effect aerobic dehydrogenation of cyclohexanones with different product selectivities. Pd(DMSO)(2)(TFA)(2) is...
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| 主要な著者: | , , |
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| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2013
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| 主題: | |
| オンライン・アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3795849/ https://ncbi.nlm.nih.gov/pubmed/23662700 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja4031648 |
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