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Aerobic Dehydrogenation of Cyclohexanone to Cyclohexenone Catalyzed by Pd(DMSO)(2)(TFA)(2): Evidence for Ligand-Controlled Chemoselectivity
The dehydrogenation of cyclohexanones affords cyclohexenones or phenols via removal of one or two equivalents of H(2), respectively. We recently reported several Pd(II) catalyst systems that effect aerobic dehydrogenation of cyclohexanones with different product selectivities. Pd(DMSO)(2)(TFA)(2) is...
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| Hlavní autoři: | , , |
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| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
2013
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3795849/ https://ncbi.nlm.nih.gov/pubmed/23662700 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja4031648 |
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