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Aerobic Dehydrogenation of Cyclohexanone to Cyclohexenone Catalyzed by Pd(DMSO)(2)(TFA)(2): Evidence for Ligand-Controlled Chemoselectivity

The dehydrogenation of cyclohexanones affords cyclohexenones or phenols via removal of one or two equivalents of H(2), respectively. We recently reported several Pd(II) catalyst systems that effect aerobic dehydrogenation of cyclohexanones with different product selectivities. Pd(DMSO)(2)(TFA)(2) is...

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書誌詳細
主要な著者: Diao, Tianning, Pun, Doris, Stahl, Shannon S.
フォーマット: Artigo
言語:Inglês
出版事項: 2013
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC3795849/
https://ncbi.nlm.nih.gov/pubmed/23662700
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja4031648
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