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Computational and experimental approaches to the molecular structure of the HCl adduct of Me(3)PO
The reaction of anhydrous HCl((g)) with trimethyl phosphane oxide yields trimethylhydroxy phosphonium chloride. A crystal structure analysis showed that the prevalent mesomeric structure in the solid state is the phosphonium chloride ion pair. Ab initio calculations in the gas phase cannot reproduce...
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| Main Authors: | , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
Elsevier
2010
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3779084/ https://ncbi.nlm.nih.gov/pubmed/24068981 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.crci.2010.07.006 |
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